2,2′:6′,2′′-Terpyridine 1,1′′-dioxide dihydrate
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Op-brai150133 2249..2262
Intractable focal epilepsy is a devastating disorder with profound effects on cognition and quality of life. Epilepsy surgery can lead to seizure freedom in patients with focal epilepsy; however, sometimes it fails due to an incomplete delineation of the epileptogenic zone. Brain networks in epilepsy can be studied with resting-state functional connectivity analysis, yet previous investigations...
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The title compound, [Cu(2)(C(4)H(4)O(4))(C(15)H(11)N(3))(2)(H(2)O)(2)](NO(3))(2)·2H(2)O, was synthesized under hydro-thermal conditions. The dinuclear copper complex is located on a crystallographic inversion centre. The Cu(II) ion is penta-coordinated in a tetra-gonal-pyramidal geometry, with one O atom of a succinate dianion and three N atoms of a 2,2':6',2''-terpyridine ligand occupying the ...
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The title complex, [Fe(C(15)H(10)ClN(3))(2)](NO(3))(2)·2H(2)O, has a six-coordinate iron(II) center balanced by two nitrate anions. The Fe atom lies on a twofold rotation axis. The complex exhibits an octa-hedral coordination configuration, where the dihedral angle between the two planar tridentate ligands is 92.4 (1)°. The crystal structure involves O-H⋯O hydrogen bonds.
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2005
ISSN: 1600-5368
DOI: 10.1107/s1600536805003855